We train a MOS prediction model based on wav2vec 2.0 using the open-access data sets BVCC and SOMOS. Our test with neural TTS data in the low-resource language (LRL) West Frisian shows that pre-training on BVCC before fine-tuning on SOMOS leads to the best accuracy for both fine-tuned and zero-shot prediction. Further fine-tuning experiments show that using more than 30 percent of the total data does not lead to significant improvements. In addition, fine-tuning with data from a single listener shows promising system-level accuracy, supporting the viability of one-participant pilot tests. These findings can all assist the resource-conscious development of TTS for LRLs by progressing towards better zero-shot MOS prediction and informing the design of listening tests, especially in early-stage evaluation.

We demonstrate the reversible in-situ photoreduction of molecular junctions of phosphomolybdate [PMo12O40]3- monolayer self-assembled on flat gold electrodes, connected by the tip of a conductive atomic force microscope. The conductance of the one electron reduced [PMo12O40]4- molecular junction is increased by 10, this open-shell state is stable in the junction in air at room temperature. The analysis of a large current-voltage dataset by unsupervised machine learning and clustering algorithms reveals that the electron transport in the pristine phosphomolybdate junctions leads to symmetric current-voltage curves, controlled by the lowest unoccupied molecular orbital (LUMO) at 0.6-0.7 eV above the Fermi energy with 25% of the junctions having a better electronic coupling to the electrodes than the main part of the dataset. This analysis also shows that a small fraction ( 18% of the dataset) of the molecules is already reduced. The UV light in-situ photoreduced phosphomolybdate junctions are systematically featuring slightly asymmetric current-voltage behaviors, which is ascribed to electron transport mediated by the single occupied molecular orbital (SOMO) nearly at resonance with the Fermi energy of the electrode and by a closely located single unoccupied molecular orbital (SUMO) at 0.3 eV above the SOMO with a weak electronic coupling to the electrodes ( 50% of the dataset) or at 0.4 eV but with a better electrode coupling ( 50% of the dataset).