This review presents a comprehensive survey and benchmark of pulse shape discrimination (PSD) algorithms for radiation detection, classifying nearly sixty methods into statistical (time-domain, frequency-domain, neural network-based) and prior-knowledge (machine learning, deep learning) paradigms. We implement and evaluate all algorithms on two standardized datasets: an unlabeled set from a 241Am-9Be source and a time-of-flight labeled set from a 238Pu-9Be source, using metrics including Figure of Merit (FOM), F1-score, ROC-AUC, and inter-method correlations. Our analysis reveals that deep learning models, particularly Multi-Layer Perceptrons (MLPs) and hybrid approaches combining statistical features with neural regression, often outperform traditional methods. We discuss architectural suitabilities, the limitations of FOM, alternative evaluation metrics, and performance across energy thresholds. Accompanying this work, we release an open-source toolbox in Python and MATLAB, along with the datasets, to promote reproducibility and advance PSD research.

An essential metric for the quality of a particle-identification experiment is its statistical power to discriminate between signal and background. Pulse shape discrimination (PSD) is a basic method for this purpose in many nuclear, high-energy and rare-event search experiments where scintillation detectors are used. Conventional techniques exploit the difference between decay-times of the pulses from signal and background events or pulse signals caused by different types of radiation quanta to achieve good discrimination. However, such techniques are efficient only when the total light-emission is sufficient to get a proper pulse profile. This is only possible when adequate amount of energy is deposited from recoil of the electrons or the nuclei of the scintillator materials caused by the incident particle on the detector. But, rare-event search experiments like direct search for dark matter do not always satisfy these conditions. Hence, it becomes imperative to have a method that can deliver a very efficient discrimination in these scenarios. Neural network based machine-learning algorithms have been used for classification problems in many areas of physics especially in high-energy experiments and have given better results compared to conventional techniques. We present the results of our investigations of two network based methods \viz Dense Neural Network and Recurrent Neural Network, for pulse shape discrimination and compare the same with conventional methods.