Nitrate ($\text{NO}_3^-$) is a form of dissolved inorganic nitrogen derived primarily from anthropogenic sources. The recent increase in river-discharged nitrate poses a major risk for coral bleaching in the Great Barrier Reef (GBR) lagoon. Although nitrate is an optically inactive (i.e., colourless) constituent, previous studies have demonstrated there is an indirect, non-causal relationship between water surface nitrate and water-leaving reflectance that is mediated through optically active water quality parameters such as total suspended solids and coloured dissolved organic matter. This work aims to advance our understanding of this relationship with an effort to measure time-series nitrate and simultaneous hyperspectral reflectance at the Fitzroy River estuary, Queensland, Australia. Time-series observations revealed periodic cycles in nitrate loads due to the tidal influence in the estuarine study site. The water surface nitrate loads were predicted from hyperspectral reflectance and water salinity measurements, with hyperspectral reflectance indicating the concentrations of optically active variables and salinity indicating the mixing of river water and seawater proportions. The accuracy assessment of model-predicted nitrate against in-situ measured nitrate values showed that the predicted nitrate values correlated well with the ground-truth data, with an $R^2$ score of 0.86, and an RMSE of 0.03 mg/L. This work demonstrates the feasibility of predicting water surface nitrate from hyperspectral reflectance and salinity measurements.

Precision agriculture, enhanced by artificial intelligence (AI), offers promising tools such as remote sensing, intelligent irrigation, fertilization management, and crop simulation to improve agricultural efficiency and sustainability. Reinforcement learning (RL), in particular, has outperformed traditional methods in optimizing yields and resource management. However, widespread AI adoption is limited by gaps between algorithmic recommendations and farmers' practical experience, local knowledge, and traditional practices. To address this, our study emphasizes Human-AI Interaction (HAII), focusing on transparency, usability, and trust in RL-based farm management. We employ a well-established trust framework - comprising ability, benevolence, and integrity - to develop a novel mathematical model quantifying farmers' confidence in AI-based fertilization strategies. Surveys conducted with farmers for this research reveal critical misalignments, which are integrated into our trust model and incorporated into a multi-objective RL framework. Unlike prior methods, our approach embeds trust directly into policy optimization, ensuring AI recommendations are technically robust, economically feasible, context-aware, and socially acceptable. By aligning technical performance with human-centered trust, this research supports broader AI adoption in agriculture.

Wastewater treatment plants are increasingly recognized as promising candidates for machine learning applications, due to their societal importance and high availability of data. However, their varied designs, operational conditions, and influent characteristics hinder straightforward automation. In this study, we use data from a pilot reactor at the Veas treatment facility in Norway to explore how machine learning can be used to optimize biological nitrate ($\mathrm{NO_3^-}$) reduction to molecular nitrogen ($\mathrm{N_2}$) in the biogeochemical process known as \textit{denitrification}. Rather than focusing solely on predictive accuracy, our approach prioritizes understanding the foundational requirements for effective data-driven modelling of wastewater treatment. Specifically, we aim to identify which process parameters are most critical, the necessary data quantity and quality, how to structure data effectively, and what properties are required by the models. We find that nonlinear models perform best on the training and validation data sets, indicating nonlinear relationships to be learned, but linear models transfer better to the unseen test data, which comes later in time. The variable measuring the water temperature has a particularly detrimental effect on the models, owing to a significant change in distributions between training and test data. We therefore conclude that multiple years of data is necessary to learn robust machine learning models. By addressing foundational elements, particularly in the context of the climatic variability faced by northern regions, this work lays the groundwork for a more structured and tailored approach to machine learning for wastewater treatment. We share publicly both the data and code used to produce the results in the paper.

Research on jailbreaking has been valuable for testing and understanding the safety and security issues of large language models (LLMs). In this paper, we introduce Iterative Refinement Induced Self-Jailbreak (IRIS), a novel approach that leverages the reflective capabilities of LLMs for jailbreaking with only black-box access. Unlike previous methods, IRIS simplifies the jailbreaking process by using a single model as both the attacker and target. This method first iteratively refines adversarial prompts through self-explanation, which is crucial for ensuring that even well-aligned LLMs obey adversarial instructions. IRIS then rates and enhances the output given the refined prompt to increase its harmfulness. We find IRIS achieves jailbreak success rates of 98% on GPT-4 and 92% on GPT-4 Turbo in under 7 queries. It significantly outperforms prior approaches in automatic, black-box and interpretable jailbreaking, while requiring substantially fewer queries, thereby establishing a new standard for interpretable jailbreaking methods.

This study examines how artificial intelligence (AI), especially Reinforcement Learning (RL), can be used in farming to boost crop yields, fine-tune nitrogen use and watering, and reduce nitrate runoff and greenhouse gases, focusing on Nitrous Oxide (N$_2$O) emissions from soil. Facing climate change and limited agricultural knowledge, we use Partially Observable Markov Decision Processes (POMDPs) with a crop simulator to model AI agents' interactions with farming environments. We apply deep Q-learning with Recurrent Neural Network (RNN)-based Q networks for training agents on optimal actions. Also, we develop Machine Learning (ML) models to predict N$_2$O emissions, integrating these predictions into the simulator. Our research tackles uncertainties in N$_2$O emission estimates with a probabilistic ML approach and climate variability through a stochastic weather model, offering a range of emission outcomes to improve forecast reliability and decision-making. By incorporating climate change effects, we enhance agents' climate adaptability, aiming for resilient agricultural practices. Results show these agents can align crop productivity with environmental concerns by penalizing N$_2$O emissions, adapting effectively to climate shifts like warmer temperatures and less rain. This strategy improves farm management under climate change, highlighting AI's role in sustainable agriculture.

For large language models (LLMs) to be trusted by humans they need to be well-calibrated in the sense that they can accurately assess and communicate how likely it is that their predictions are correct. Recent work has focused on the quality of internal LLM confidence assessments, but the question remains of how well LLMs can communicate this internal model confidence to human users. This paper explores the disparity between external human confidence in an LLM's responses and the internal confidence of the model. Through experiments involving multiple-choice questions, we systematically examine human users' ability to discern the reliability of LLM outputs. Our study focuses on two key areas: (1) assessing users' perception of true LLM confidence and (2) investigating the impact of tailored explanations on this perception. The research highlights that default explanations from LLMs often lead to user overestimation of both the model's confidence and its' accuracy. By modifying the explanations to more accurately reflect the LLM's internal confidence, we observe a significant shift in user perception, aligning it more closely with the model's actual confidence levels. This adjustment in explanatory approach demonstrates potential for enhancing user trust and accuracy in assessing LLM outputs. The findings underscore the importance of transparent communication of confidence levels in LLMs, particularly in high-stakes applications where understanding the reliability of AI-generated information is essential.

Agricultural management, with a particular focus on fertilization strategies, holds a central role in shaping crop yield, economic profitability, and environmental sustainability. While conventional guidelines offer valuable insights, their efficacy diminishes when confronted with extreme weather conditions, such as heatwaves and droughts. In this study, we introduce an innovative framework that integrates Deep Reinforcement Learning (DRL) with Recurrent Neural Networks (RNNs). Leveraging the Gym-DSSAT simulator, we train an intelligent agent to master optimal nitrogen fertilization management. Through a series of simulation experiments conducted on corn crops in Iowa, we compare Partially Observable Markov Decision Process (POMDP) models with Markov Decision Process (MDP) models. Our research underscores the advantages of utilizing sequential observations in developing more efficient nitrogen input policies. Additionally, we explore the impact of climate variability, particularly during extreme weather events, on agricultural outcomes and management. Our findings demonstrate the adaptability of fertilization policies to varying climate conditions. Notably, a fixed policy exhibits resilience in the face of minor climate fluctuations, leading to commendable corn yields, cost-effectiveness, and environmental conservation. However, our study illuminates the need for agent retraining to acquire new optimal policies under extreme weather events. This research charts a promising course toward adaptable fertilization strategies that can seamlessly align with dynamic climate scenarios, ultimately contributing to the optimization of crop management practices.

Climate change has increased the frequency and severity of extreme weather events such as hurricanes and winter storms. The complex interplay of floods with tides, runoff, and sediment creates additional hazards -- including erosion and the undermining of urban infrastructure -- consequently impacting the health of our rivers and ecosystems. Observations of these underwater phenomena are rare, because satellites and sensors mounted on aerial vehicles cannot penetrate the murky waters. Autonomous Surface Vehicles (ASVs) provides a means to track and map these complex and dynamic underwater phenomena. This work highlights preliminary results of high-resolution data gathering with ASVs, equipped with a suite of sensors capable of measuring physical and chemical parameters of the river. Measurements were acquired along the lower Schuylkill River in the Philadelphia area at high-tide and low-tide conditions. The data will be leveraged to improve our understanding of changes in bathymetry due to floods; the dynamics of mixing and stagnation zones and their impact on water quality; and the dynamics of suspension and resuspension of fine sediment. The data will also provide insight into the development of adaptive sampling strategies for ASVs that can maximize the information gain for future field experiments.