For Prognostics and Health Management (PHM) of Lithium-ion (Li-ion) batteries, many models have been established to characterize their degradation process. The existing empirical or physical models can reveal important information regarding the degradation dynamics. However, there are no general and flexible methods to fuse the information represented by those models. Physics-Informed Neural Network (PINN) is an efficient tool to fuse empirical or physical dynamic models with data-driven models. To take full advantage of various information sources, we propose a model fusion scheme based on PINN. It is implemented by developing a semi-empirical semi-physical Partial Differential Equation (PDE) to model the degradation dynamics of Li-ion batteries. When there is little prior knowledge about the dynamics, we leverage the data-driven Deep Hidden Physics Model (DeepHPM) to discover the underlying governing dynamic models. The uncovered dynamics information is then fused with that mined by the surrogate neural network in the PINN framework. Moreover, an uncertainty-based adaptive weighting method is employed to balance the multiple learning tasks when training the PINN. The proposed methods are verified on a public dataset of Li-ion Phosphate (LFP)/graphite batteries.

Lithium-ion (Li-ion) batteries are the primary power source in various applications due to their high energy and power density. Their market was estimated to be up to 48 billion U.S. dollars in 2022. However, the widespread adoption of Li-ion batteries has resulted in counterfeit cell production, which can pose safety hazards to users. Counterfeit cells can cause explosions or fires, and their prevalence in the market makes it difficult for users to detect fake cells. Indeed, current battery authentication methods can be susceptible to advanced counterfeiting techniques and are often not adaptable to various cells and systems. In this paper, we improve the state of the art on battery authentication by proposing two novel methodologies, DCAuth and EISthentication, which leverage the internal characteristics of each cell through Machine Learning models. Our methods automatically authenticate lithium-ion battery models and architectures using data from their regular usage without the need for any external device. They are also resilient to the most common and critical counterfeit practices and can scale to several batteries and devices. To evaluate the effectiveness of our proposed methodologies, we analyze time-series data from a total of 20 datasets that we have processed to extract meaningful features for our analysis. Our methods achieve high accuracy in battery authentication for both architectures (up to 0.99) and models (up to 0.96). Moreover, our methods offer comparable identification performances. By using our proposed methodologies, manufacturers can ensure that devices only use legitimate batteries, guaranteeing the operational state of any system and safety measures for the users.

In this paper, we present a physics-informed neural network (PINN) approach for predicting the performance of an all-vanadium redox flow battery, with its physics constraints enforced by a two-dimensional (2D) mathematical model. The 2D model, which includes 6 governing equations and 24 boundary conditions, provides a detailed representation of the electrochemical reactions, mass transport and hydrodynamics occurring inside the redox flow battery. To solve the 2D model with the PINN approach, a composite neural network is employed to approximate species concentration and potentials; the input and output are normalized according to prior knowledge of the battery system; the governing equations and boundary conditions are first scaled to an order of magnitude around 1, and then further balanced with a self-weighting method. Our numerical results show that the PINN is able to predict cell voltage correctly, but the prediction of potentials shows a constant-like shift. To fix the shift, the PINN is enhanced by further constrains derived from the current collector boundary. Finally, we show that the enhanced PINN can be even further improved if a small number of labeled data is available.

High-dimensional linear regression is important in many scientific fields. This article considers discrete measured data of underlying smooth latent processes, as is often obtained from chemical or biological systems. Interpretation in high dimensions is challenging because the nullspace and its interplay with regularization shapes regression coefficients. The data's nullspace contains all coefficients that satisfy $\mathbf{Xw}=\mathbf{0}$, thus allowing very different coefficients to yield identical predictions. We developed an optimization formulation to compare regression coefficients and coefficients obtained by physical engineering knowledge to understand which part of the coefficient differences are close to the nullspace. This nullspace method is tested on a synthetic example and lithium-ion battery data. The case studies show that regularization and z-scoring are design choices that, if chosen corresponding to prior physical knowledge, lead to interpretable regression results. Otherwise, the combination of the nullspace and regularization hinders interpretability and can make it impossible to obtain regression coefficients close to the true coefficients when there is a true underlying linear model. Furthermore, we demonstrate that regression methods that do not produce coefficients orthogonal to the nullspace, such as fused lasso, can improve interpretability. In conclusion, the insights gained from the nullspace perspective help to make informed design choices for building regression models on high-dimensional data and reasoning about potential underlying linear models, which are important for system optimization and improving scientific understanding.

Capacity attenuation is one of the most intractable issues in the current of application of the cells. The disintegration mechanism is well known to be very complex across the system. It is a great challenge to fully comprehend this process and predict the process accurately. Thus, the machine learning (ML) technology is employed to predict the specific capacity change of the cell throughout the cycle and grasp this intricate procedure. Different from the previous work, according to the WOA-ELM model proposed in this work (R2 = 0.9999871), the key factors affecting the specific capacity of the battery are determined, and the defects in the machine learning black box are overcome by the interpretable model. Their connection with the structural damage of electrode materials and battery failure during battery cycling is comprehensively explained, revealing their essentiality to battery performance, which is conducive to superior research on contemporary batteries and modification.

This study develops a methodology by capturing both the battery aging state and degradation rate for improved life prediction performance. The aging state is indicated by six physical features of an equivalent circuit model that are extracted from the voltage relaxation data. And the degradation rate is captured by two features extracted from the differences between the voltage relaxation curves within a moving window (for life prediction), or the differences between the capacity vs. voltage curves at different cycles (for life classification). Two machine learning models, which are constructed based on Gaussian Processes, are used to describe the relationships between these physical features and battery lifetimes for the life prediction and classification, respectively. The methodology is validated with the aging data of 74 battery cells of three different types. Experimental results show that based on only 3-12 minutes' sampling data, the method with novel features predicts accurate battery lifetimes, with the prediction accuracy improved by up to 67.09% compared with the benchmark method. And the batteries are classified into three groups (long, medium, and short) with an overall accuracy larger than 90% based on only two adjacent cycles' information, enabling the highly efficient regrouping of retired batteries.

The advent of artificial intelligence (AI) has enabled a comprehensive exploration of materials for various applications. However, AI models often prioritize frequently encountered materials in the scientific literature, limiting the selection of suitable candidates based on inherent physical and chemical properties. To address this imbalance, we have generated a dataset of 1,494,017 natural language-material paragraphs based on combined OQMD, Materials Project, JARVIS, COD and AFLOW2 databases, which are dominated by ab initio calculations and tend to be much more evenly distributed on the periodic table. The generated text narratives were then polled and scored by both human experts and ChatGPT-4, based on three rubrics: technical accuracy, language and structure, and relevance and depth of content, showing similar scores but with human-scored depth of content being the most lagging. The merger of multi-modality data sources and large language model (LLM) holds immense potential for AI frameworks to help the exploration and discovery of solid-state materials for specific applications.

Deep learning (DL) has gained popularity in recent years as an effective tool for classifying the current health and predicting the future of industrial equipment. However, most DL models have black-box components with an underlying structure that is too complex to be interpreted and explained to human users. This presents significant challenges when deploying these models for safety-critical maintenance tasks, where non-technical personnel often need to have complete trust in the recommendations these models give. To address these challenges, we utilize a convolutional neural network (CNN) with Gradient-weighted Class Activation Mapping (Grad-CAM) activation map visualizations to form an interpretable DL method for classifying bearing faults. After the model training process, we apply Grad-CAM to identify a training sample's feature importance and to form a library of diagnosis knowledge (or health library) containing training samples with annotated feature maps. During the model evaluation process, the proposed approach retrieves prediction basis samples from the health library according to the similarity of the feature importance. The proposed method can be easily applied to any CNN model without modifying the model architecture, and our experimental results show that this method can select prediction basis samples that are intuitively and physically meaningful, improving the model's trustworthiness for human users.

To make its Ultium EV program a success, GM is counting on battery innovations to make the technology simpler and cheaper. As part of that program, the automaker has boosted its investment with Mitra Chem --a company focused on building batteries in the US using iron-based cathodes -- via a new $60 million financing round. "This is a strategic investment that will further help reinforce GM's efforts in EV batteries, accelerate our work on affordable battery chemistries like LMFP and support our efforts to build a US-focused battery supply chain," said GM VP Gil Golan. Mitra Chem is more of a battery development company than a manufacturer. It uses AI to "simulate, synthesize and test thousands of cathode designs monthly, ranging in size from grams to kilograms," the press release states.

The degradation process of lithium-ion batteries is intricately linked to their entire lifecycle as power sources and energy storage devices, encompassing aspects such as performance delivery and cycling utilization. Consequently, the accurate and expedient estimation or prediction of the aging state of lithium-ion batteries has garnered extensive attention. Nonetheless, prevailing research predominantly concentrates on either aging estimation or prediction, neglecting the dynamic fusion of both facets. This paper proposes a hybrid model for capacity aging estimation and prediction based on deep learning, wherein salient features highly pertinent to aging are extracted from charge and discharge relaxation processes. By amalgamating historical capacity decay data, the model dynamically furnishes estimations of the present capacity and forecasts of future capacity for lithium-ion batteries. Our approach is validated against a novel dataset involving charge and discharge cycles at varying rates. Specifically, under a charging condition of 0.25C, a mean absolute percentage error (MAPE) of 0.29% is achieved. This outcome underscores the model's adeptness in harnessing relaxation processes commonly encountered in the real world and synergizing with historical capacity records within battery management systems (BMS), thereby affording estimations and prognostications of capacity decline with heightened precision.